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Eliminación de fluoxetina presente en aguas contaminadas usando procesos fotoquímicos de oxidación avanzada y luz solar
Eliminación de fluoxetina presente en aguas contaminadas usando procesos fotoquímicos de oxidación avanzada y luz solar
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Eliminación de fluoxetina presente en aguas contaminadas usando procesos fotoquímicos de oxidación avanzada y luz solar. (2019). Revista EIA, 16(32), 27-42. https://doi.org/10.24050/reia.v16i32.1081
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Se estudió comparativamente la degradación de la fluoxetina por medio de tres procesos fotoquímicos de oxidación avanzada: foto Fenton (FFS), foto electro Fenton (FEFS) y fotocatálisis con TiO2 (FCS), mediados por radiación solar. Los experimentos se desarrollaron con soluciones de 100 mL en un vaso de reacción y para el caso de FEFS, se equipó el reactor con un ánodo de IrO2/RuO2 y un cátodo de grafito de difusión de aire para producción continua de peróxido. En todos los casos se hizo seguimiento de la degradación, la mineralización de la fluoxetina y la toxicidad. El proceso FFS presentó la mayor velocidad de degradación y mineralización, así como las mayores eficiencias en la degradación y mineralización. El pH en el proceso FFS definió el alcance de la mineralización, evidenciando que a pH ácido se logra mayor mineralización pues se evita la formación de complejos e hidróxidos típicos de un pH mayor. El proceso FCS presenta alta eficiencia, pero cinéticas lentas. La toxicidad ante levadura de cerveza disminuye a medida que se generan subproductos de degradación en todos los procesos evaluados.
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- Affam, A. C., Chaudhuri, M., Kutty, S. R. M., & Muda, K. (2014). UV Fenton and sequencing batch reactor treatment of chlorpyrifos, cypermethrin and chlorothalonil pesticide wastewater. International Biodeterioration & Biodegradation, 93, 195–201. https://doi.org/10.1016/j.ibiod.2014.06.002
- Bandala, V. E. E. R., Bautista, P., Mohedano, A. F., Casas, J. A., Zazo, J. A., Rodriguez, J. J., … Wang, Y. (2010). Degradation of fifteen emerging contaminants at microg L(-1) initial concentrations by mild solar photo-Fenton in MWTP effluents. Water Research, 44(2), 545–54. https://doi.org/10.1016/j.watres.2009.09.059
- Castro, A. De, Concheiro, M., Quintela, Ó., & Cruz, A. (2005). Detección de fluoxetina y su metabolito activo norfluoxetina mediante LC-MS en plasma y saliva . Revista de Toxicología, 22(Su1), 142–149.
- De la Cruz, N., Giménez, J., Esplugas, S., Grandjean, D., de Alencastro, L. F., & Pulgarín, C. (2012). Degradation of 32 emergent contaminants by UV and neutral photo-fenton in domestic wastewater effluent previously treated by activated sludge. Water Research, 46(6), 1947–57. https://doi.org/10.1016/j.watres.2012.01.014
- Feng, H. E., & Le-cheng, L. E. I. (2004). Degradation kinetics and mechanisms of phenol in photo-Fenton process *, 5(2), 198–205.
- Flores, N., Sirés, I., Garrido, J. A., Centellas, F., Rodríguez, R. M., Cabot, P. L., & Brillas, E. (2015). Degradation of trans-ferulic acid in acidic aqueous medium by anodic oxidation, electro-Fenton and photoelectro-Fenton. Journal of Hazardous Materials, 1–10. https://doi.org/10.1016/j.jhazmat.2015.11.040
- Giraldo-Aguirre, A. L., Erazo-Erazo, E. D., Flórez-Acosta, O. A., Serna-Galvis, E. A., & Torres-Palma, R. A. (2015). TiO2 photocatalysis applied to the degradation and antimicrobial activity removal of oxacillin: Evaluation of matrix components, experimental parameters, degradation pathways and identification of organics by-products. Journal of Photochemistry and Photobiology A: Chemistry, 311, 95–103. https://doi.org/10.1016/j.jphotochem.2015.06.021
- Giraldo, A. L., Peñuela, G. a., Torres-Palma, R. a., Pino, N. J., Palominos, R. a., & Mansilla, H. D. (2010). Degradation of the antibiotic oxolinic acid by photocatalysis with TiO2 in suspension. Water Research, 44(18), 5158–5167. https://doi.org/10.1016/j.watres.2010.05.011
- Guzmán, J., Mosteo, R., Sarasa, J., Alba, J. A., & Ovelleiro, J. L. (2016). Evaluation of solar photo-Fenton and ozone based processes as citrus wastewater pre-treatments. Separation and Purification Technology, 164, 155–162. https://doi.org/10.1016/j.seppur.2016.03.025
- Honda, V., Silva, O., Paula, A., Silva, A. C., Teixeira, C.,
- Borrely, S. I., … Costa, S. (2016). Degradation and acute toxicity removal of the antidepressant Fluoxetine ( Prozac ® ) in aqueous systems by electron beam irradiation. Environmental Science and Pollution Research, 11927–11936. https://doi.org/10.1007/s11356-016-6410-1
- Klamerth, N., Malato, S., Agüera, A., & Fernández-Alba, A. (2013). Photo-Fenton and modified photo-Fenton at neutral pH for the treatment of emerging contaminants in wastewater treatment plant effluents: A comparison. Water Research, 47(2), 833–840. https://doi.org/10.1016/j.watres.2012.11.008
- Klamerth, N., Rizzo, L., Malato, S., Maldonado, M. I., Agüera, A., & Fernández-Alba, A. R. (2010). Degradation of fifteen emerging contaminants at µg L-1 initial concentrations by mild solar photo-Fenton in MWTP effluents. Water Research, 44(2), 545–554. https://doi.org/10.1016/j.watres.2009.09.059
- Li, W., Nanaboina, V., Zhou, Q., & Korshin, G. V. (2011). Effects of Fenton treatment on the properties of effluent organic matter and their relationships with the degradation of pharmaceuticals and personal care products. Water Research, 46(2), 403–412. https://doi.org/10.1016/j.watres.2011.11.002
- Luna, R. A., Zermeño, B. B., Moctezuma, E., Contreras, R. E., Leyva, E., & López B, M. A. (2013). FOTODEGRADACIÓN DE OMEPRAZOL EN SOLUCIÓN ACUOSA UTILIZANDO TiO2 COMO CATALIZADOR. Revista Mexicana de Ingeniería Química, 12(1), 85–95.
- Méndez-Arriaga, F., Otsu, T., Oyama, T., Gimenez, J., Esplugas, S., Hidaka, H., & Serpone, N. (2011). Photooxidation of the antidepressant drug Fluoxetine ( Prozac ® ) in aqueous media by hybrid catalytic / ozonation processes. Water Research, 45, 2782–2794. https://doi.org/10.1016/j.watres.2011.02.030
- Perini, J. A. D. L., Costa, B., Tonetti, A. L., & Nogueira, R. F. P. (2016). Photo-Fenton degradation of the pharmaceuticals ciprofloxacin and fluoxetine after anaerobic pre-treatment of hospital effluent. Environmental Science and Pollution Research. https://doi.org/10.1007/s11356-016-7416-4
- Pimentel, M., Oturan, N., Dezotti, M., & Oturan, M. A. (2008). Phenol degradation by advanced electrochemical oxidation process electro-Fenton using a carbon felt cathode, 83, 140–149. https://doi.org/10.1016/j.apcatb.2008.02.011
- Salazar, C., Ridruejo, C., Brillas, E., Yáñez, J., Mansilla, H. D., & Sirés, I. (2016). Abatement of the fluorinated antidepressant fluoxetine ( Prozac ) and its reaction by electrochemical advanced methods. “Applied Catalysis B, Environmental.” https://doi.org/10.1016/j.apcatb.2016.10.026
- Serna-galvis, E. A., Silva-agredo, J., Giraldo, A. L., Flórez-acosta, O. A., & Torres-palma, R. A. (2016). Comparative study of the effect of pharmaceutical additives on the elimination of antibiotic activity during the treatment of oxacillin in water by the photo-Fenton , TiO 2 -photocatalysis and electrochemical processes. Science of the Total Environment, The, 541, 1431–1438. https://doi.org/10.1016/j.scitotenv.2015.10.029
- Su, C., Bellotindos, L. M., Chang, A., & Lu, M. (2013). Degradation of acetaminophen in an aerated Fenton reactor. Journal of the Taiwan Institute of Chemical Engineers, 44(2), 309–315. https://doi.org/10.1016/j.jtice.2012.11.009
- Su, C. C., Chang, A. T., Bellotindos, L. M., & Lu, M. C. (2012). Degradation of acetaminophen by Fenton and electro-Fenton processes in aerator reactor. Separation and Purification Technology. https://doi.org/10.1016/j.seppur.2012.07.004
- Villegas-Guzman, P., Silva-Agredo, J., González-Gómez, D., Giraldo-Aguirre, A. L., Flórez-Acosta, O., & Torres-Palma, R. a. (2015). Evaluation of water matrix effects, experimental parameters, and the degradation pathway during the TiO2 photocatalytical treatment of the antibiotic dicloxacillin. Journal of Environmental Science and Health. Part A, Toxic/hazardous Substances & Environmental Engineering, 50(1), 40–8. https://doi.org/10.1080/10934529.2015.964606
- Zayat, M., Garcia-parejo, P., & Levy, D. (2007). Preventing UV-light damage of light sensitive materials using a highly protective UV-absorbing coating, 1270–1281. https://doi.org/10.1039/b608888k
- Zhao, Y., Yu, G., Chen, S., Zhang, S., Wang, B., Huang, J., & Wang, Y. (2017). Ozonation of antidepressant fluoxetine and its metabolite product norfluoxitine : Kinetics , intermediates and toxicity. Chemical Engineering Journal. https://doi.org/10.1016/j.cej.2017.02.032
