AlPO-5 and SAPO-5 hydrothermal synthesis and catalytic propylen oligomerization

Síntesis hidrotermal de AlPO-5 y SAPO-5 y su evaluación catalítica en la oligomerización de propileno

Published 2020-02-09

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Vol. 17 No. 33 (2020)
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AlPO-5 and SAPO-5 hydrothermal synthesis and catalytic propylen oligomerization. (2020). Revista EIA, 17(33), 33002 pp. 1-11. https://doi.org/10.24050/reia.v17i33.1260
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https://doi.org/10.24050/reia.v17i33.1260
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Jorge Ruiz Llano
Universidad de Antioquia
Juan Camilo Arroyave Manco
Universidad de Antioquia
Johana Catalina Arboleda Echavarría
Universidad de Antioquia
Adriana Patricia Echavarría Izasa
Universidad de Antioquia
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Jorge Ruiz Llano,

Facultad de Ingeniería. Estudiante de Maestría en Ingeniería

Johana Catalina Arboleda Echavarría,

PhD Ciencias Químicas

Adriana Patricia Echavarría Izasa,

PhD Ciencias Químicas

Aluminophosphates and silicoaluminophospates are molecular sieves families with ordered pore systems with an alternative accommodation of AlO4 and PO4. This molecular sieves can be use like catalyst in propylen oligomerization reaction due their textural properties and selectivity toward some products for contribute to obtaining olefins of carbon chains longer achieving thus the synthesis of sulfur free liquid fuels. In this work, AlPO-5 and SAPO-5 were synthetize and was evaluated its catalytic activity in propylen oligomerization. Molecular sieves obtained were characterized by x-ray diffraction (XRD), thermal gravimetric analysis (TGA), atomic absorption spectrometry (AA), ammonia temperature programmed desorption (NH3-TPD) and scanning electronic microscopy (SEM). The reaction products were analyzed by gas chromatography (GC). A higher yield was obtained in the proportion of heavy oligomers after impregnation of Cr and Ni on AlPO-5, being Cr 3% AlPO-5 the catalyst with the highest yield.

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