Modeling of jump of the inverse of the resistance of NaI-AgI solid electrolyte
Modelamiento del salto del inverso de la resistencia del electrolito sólido NaI-AgI


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Electrical resistance measurements of NaI-AgI solid electrolyte showed that adding NaI to AgI stabilizes the transition from conducting ionic phase (β-AgI) to the superionic (α-AgI) at 420 K with increasing temperature. The ionic conductivity at the β → α transition of AgI increases by several orders of magnitude. Considering a phenomenological model based on a free energy density was fitted the abrupt jump of ionic conductivity. In this model, the equilibrium defect concentration (, R is the resistance) is the order parameter. Better results are achieved for the order parameter.
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